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31.
Empirical orthogonal functions (EOFs) or principal components were used to extract the significant modes of shoreline variability from several data sets collected at three very different locations. Although EOFs have proven to be a valuable tool in the analysis of nearshore data, most applications have focused on the ability of the technique to describe cross-shore or profile variability. Here however, EOFs were used to help identify the dominant modes of longshore shoreline variability at Duck, North Carolina, the Gold Coast, Australia, and at several locations within the Columbia River Littoral Cell in the U.S. Pacific Northwest. In part one of this analysis, characteristic patterns of shoreline variability identified by the EOF analysis are described in detail. At each site, the dominant modes consisting of the first four eigenfunctions were found to describe nearly 95% of the total shoreline variability. At both Duck and the Gold Coast, several interesting longshore periodic features suggestive of sand waves were identified, while boundary effects related to natural headlands and navigational structures/entrances dominated the Pacific Northwest data sets.  相似文献   
32.
33.
The Cocos plate subducts beneath North America at the Mexico trench. The northernmost segment of this trench, between the Orozco and Rivera fracture zones, has ruptured in a sequence of five large earthquakes from 1973 to 1985; the Jan. 30, 1973 Colima event (M s 7.5) at the northern end of the segment near Rivera fracture zone; the Mar. 14, 1979 Petatlan event (M s 7.6) at the southern end of the segment on the Orozco fracture zone; the Oct. 25, 1981 Playa Azul event (M s 7.3) in the middle of the Michoacan gap; the Sept. 19, 1985 Michoacan mainshock (M s 8.1); and the Sept. 21, 1985 Michoacan aftershock (M s 7.6) that reruptured part of the Petatlan zone. Body wave inversion for the rupture process of these earthquakes finds the best: earthquake depth; focal mechanism; overall source time function; and seismic moment, for each earthquake. In addition, we have determined spatial concentrations of seismic moment release for the Colima earthquake, and the Michoacan mainshock and aftershock. These spatial concentrations of slip are interpreted as asperities; and the resultant asperity distribution for Mexico is compared to other subduction zones. The body wave inversion technique also determines theMoment Tensor Rate Functions; but there is no evidence for statistically significant changes in the moment tensor during rupture for any of the five earthquakes. An appendix describes theMoment Tensor Rate Functions methodology in detail.The systematic bias between global and regional determinations of epicentral locations in Mexico must be resolved to enable plotting of asperities with aftershocks and geographic features. We have spatially shifted all of our results to regional determinations of epicenters. The best point source depths for the five earthquakes are all above 30 km, consistent with the idea that the down-dip edge of the seismogenic plate interface in Mexico is shallow compared to other subduction zones. Consideration of uncertainties in the focal mechanisms allows us to state that all five earthquakes occurred on fault planes with the same strike (N65°W to N70°W) and dip (15±3°), except for the smaller Playa Azul event at the down-dip edge which has a steeper dip angle of 20 to 25°. However, the Petatlan earthquake does prefer a fault plane that is rotated to a more east-west orientation—one explanation may be that this earthquake is located near the crest of the subducting Orozco fracture zone. The slip vectors of all five earthquakes are similar and generally consistent with the NUVEL-predicted Cocos-North America convergence direction of N33°E for this segment. The most important deviation is the more northerly slip direction for the Petatlan earthquake. Also, the slip vectors from the Harvard CMT solutions for large and small events in this segment prefer an overall convergence direction of about N20°E to N25°E.All five earthquakes share a common feature in the rupture process: each earthquake has a small initial precursory arrival followed by a large pulse of moment release with a distinct onset. The delay time varies from 4 s for the Playa Azul event to 8 s for the Colima event. While there is some evidence of spatial concentration of moment release for each event, our overall asperity distribution for the northern Mexico segment consists of one clear asperity, in the epicentral region of the 1973 Colima earthquake, and then a scattering of diffuse and overlapping regions of high moment release for the remainder of the segment. This character is directly displayed in the overlapping of rupture zones between the 1979 Petatlan event and the 1985 Michoacan aftershock. This character of the asperity distribution is in contrast to the widely spaced distinct asperities in the northern Japan-Kuriles Islands subduction zone, but is somewhat similar to the asperity distributions found in the central Peru and Santa Cruz Islands subduction zones. Subduction of the Orozco fracture zone may strongly affect the seismogenic character as the overlapping rupture zones are located on the crest of the subducted fracture zone. There is also a distinct change in the physiography of the upper plate that coincides with the subducting fracture zone, and the Guerrero seismic gap to the south of the Petatlan earthquake is in the wake of the Orozco fracture zone. At the northern end, the Rivera fracture zone in the subducting plate and the Colima graben in the upper plate coincide with the northernmost extent of the Colima rupture zone.  相似文献   
34.
Internally consistent thermodynamic data, including their uncertainties and correlations, are reported for 22 phases of the quaternary system CaO-Al2O3-SiO2-H2O. These data have been derived by simultaneous evaluation of the appropriate phase properties (PP) and reaction properties (RP) by the novel technique of Bayes estimation (BE). The thermodynamic model used and the theory of BE was expounded in Part I of this paper. Part II is the follow-up study illustrating an application of BE. The input for BE comprised, among others, the a priori values for standard enthalpy of formation of the i-th phase, Δf H i 0 , and its standard entropy, S i 0 , in addition to the reaction reversal constraints for 33 equilibria involving the relevant phases. A total of 269 RP restrictions have been processed, of which 107 turned out to be non-redundant. The refined values for Δf H i 0 and S i 0 obtained by BE, including their 2σ-uncertainties, appear in Table 4; the Appendix reproduces the corresponding correlation matrix. These data permit generation of computed phase diagrams with 2σ-uncertainty envelopes based on conventional error propagation; Fig. 3 depicts such a phase diagram for the system CaO-Al2O3-SiO2. It shows that the refined dataset is capable of yielding phase diagrams with uncertainty envelopes narrow enough to be geologically useful. The results in Table 4 demonstrate that the uncertainties of the prior values for Δf H i Emphasis>0 , given in Table 1, have decreased by up to an order of magnitude, while those for S i 0 improved by a factor of up to two. For comparison, Table 4 also lists the refined Δf H i 0 and S i 0 data obtained by mathematical programming (MAP), minimizing a quadratic objective function used earlier by Berman (1988). Examples of calculated phase diagrams are given to demonstrate the advantages of BE for deriving internally consistent thermodynamic data. Although P-T curves generated from both MAP and BE databases will pass through the reversal restrictions, BE datasets appear to be better suited for extrapolations beyond the P-T range explored experimentally and for predicting equilibria not constrained by reversals.  相似文献   
35.
This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of 137Cs, 134Cs and 241Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the 210Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm-2 yr-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm-2 yr-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.  相似文献   
36.
In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.  相似文献   
37.
Although parasequence and sequence are scale-independent terms, they are frequently applied only to specific scales of cycles. For example, meter-scale cycles are commonly assumed to be parasequences or PACs. In the Upper Ordovician Kope and Fairview Formations of northern Kentucky, we examined a succession of 50 meter-scale cycles that have been variously interpreted as deepening-upward, shallowing-upward, or showing no relationship with water depth. Our analysis shows that these cycles, characterized by shifts in storm-bed proximality, are highly variable in their thickness and internal construction. Most cycles are best considered high-frequency sequences, because deepening-upward intervals are common, and many cycles contain evidence of abrupt basinward shifts in facies as expected at sequence boundaries. A minority fit the parasequence model of shallowing-upward cycles bounded by flooding surfaces. Larger, 20 m scale cycles are defined by systematic thickening and thinning trends of meter-scale cycles. However, meter-scale cycles do not display any systematic trends in cycle anatomy as a function of position within the 20 m cycles or position within the Kope and Fairview Formations. The high cycle variability and the lack of systematic stratigraphic organization with respect to longer-term cyclicity reflect either the irregularity of relative sea-level changes, the poor recording of sea-level changes in this deep-water setting, or the generation of these cycles by climate-induced cyclicity in storm intensity. These three mechanisms would generate similar patterns at the outcrop scale, so it is not possible at the present to distinguish between them.  相似文献   
38.
Miller AI  Mao S 《Geology》1995,23(4):305-308
The Ordovician radiation of marine life was among the most substantial pulses of diversification in Earth history and coincided in time with a major increase in the global level of orogenic activity. To investigate a possible causal link between these two patterns, the geographic distributions of 6576 individual appearances of Ordovician vician genera around the world were evaluated with respect to their proximity to probable centers of orogeny (foreland basins). Results indicate that these genera, which belonged to an array of higher taxa that diversified in the Middle and Late Ordovician (trilobites, brachiopods, bivalves, gastropods, monoplacophorans), were far more diverse in, and adjacent to, foreland basins than they were in areas farther removed from orogenic activity (carbonate platforms). This suggests an association of orogeny with diversification at that time.  相似文献   
39.
We have used the SPO tower telescope and echelle spectrograph to study differences in the profiles of three Fei lines, between magnetic network and cells. Ca K slit-jaw pictures were used to identify the network and cell areas, and mean network and cell profiles were computed from digitized spectra for the g = 0 lines 4065, 5434, and the g = 1.5 line 5233. The profile bisectors show that the wings of all three lines are red-shifted in the network by between 75–200 m s–1 relative to the cell profiles. But the redshift decreases in the line core and becomes less than the standard error of 20 m s–1 near the line core minimum. This disappearance of the redshift at the cores of all 3 lines formed over the height range 250–500 km above 0.5 = 1, argues against a steady downflow at supergranule boundaries. We show that such red-shifted wings and a relatively unshifted core can result if granular convection is suppressed near the network flux tubes, without implying any downflow in the vicinity of these flux tubes. Our results also indicate that searches for large-scale convective velocity patterns should measure shifts of the line core, rather than the line wings which appear to be very sensitive to inhomogeneities in granule structure.Visiting Astronomers, Sacramento Peak Observatory.  相似文献   
40.
The argon isotope systematics of vein-quartz samples with two different K-reservoirs have been evaluated in detail. Potassium is hosted by ultra-high-salinity fluid inclusions in quartz samples from the Eloise and Osborne iron-oxide-copper-gold (IOCG) deposits of the Mt Isa Inlier, Australia. In contrast, K is hosted by accidentally trapped mica within lower-salinity fluid inclusions of a sample selected from the Railway Fault, 13 km south of the Mt Isa copper mine, Australia. Imprecise apparent ages have been obtained for all of the samples studied and conclusively demonstrate that quartz fluid inclusions are retentive to Ar and have not leaked over billions of years. IOCG samples that host K in fluid inclusions only, have K/Cl values of <1 and the ages obtained represent the maximum ages for mineralization. In contrast, the Railway Fault samples that include accidentally trapped mica have K/Cl values of ?1. Excess 40ArE plus Cl hosted by fluid inclusions, and radiogenic 40ArR plus K, are strongly correlated in these samples and define a plane in 3D 40Ar-36Ar-K-Cl space. In this case, the plane yields an ‘excess 40ArE’ corrected age of ∼1030 Ma that is 100’s of Ma younger than nearby Cu-mineralization at Mt Isa. The age is interpreted to reflect 40Ar-loss from the accidentally trapped mica into the surrounding fluid inclusions, and is not related to the samples’ age of formation. The initial 40Ar/36Ar value of fluid inclusions is widely used to provide information on fluid origin. For the IOCG samples that host K in fluid inclusions only, the initial 40Ar/36Ar values are close to the measured values at every temperature of stepped heating experiments. For samples that include accidentally trapped mica, the correction for post-entrapment radiogenic 40ArR production is significant. Furthermore, because 39ArK present in accidentally trapped mica crystals is released at different temperatures to radiogenic 40ArR lost to the surrounding fluid inclusions, intra-sample 40Ar/36Ar variation cannot be reliably documented. The results demonstrate that noble gas analysis is readily applicable to Proterozoic, or older, samples but that if K-mineral impurities are present within quartz the abundance of K must be determined before calculation of mean 40Ar/36Ar values that are representative of the samples’ initial composition.  相似文献   
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